My inquiry to AOAC [Fwd: Inquiry on AOAC fluorometric method for histamine content analysis]

From: Ko, Iwan Setiyono (isk025@student.uit.no)
Date: Tue Mar 14 2006 - 16:26:32 PST

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    Dear listers,

    I forwarded my inquiry to AOAC regarding its fluorometric histamine
    content analysis, to be more specific on fish and seafood products (found
    on pp. 876-877 on their manual - see REFERENCES). Basically, I was asking
    the (technical/scientific?) foundation(s) why the AOAC' expert(s) chose
    these following three points in the calibration, and I am still waiting
    for their response. Anyone checked their 1995-version manual?

    If it is merely (pure) example, they should have incorporated further
    information on this. I suppose that almost everybody knows that equipments
    shall be calibrated within their operation ranges. In this case:
    calibrating points chosen within 0 to 50 ppm (or larger) range may be more
    representative.

    The implication the AOAC manual might cause is that the commercial fish
    and seafood industries might interpret the method as it is, i.e. the
    "official" method. Tons of fish and seafood processors exporting products
    to the US may use the AOAC's histamine fluorometric test as it is
    considered as the official method recognized by the US FDA (Rogers and
    Staruszkiewicz, 1997**)

    ---------------------------- Original Message ----------------------------
    Subject: Inquiry on AOAC fluorometric method for histamine content
    analysis From: "Ko, Iwan Setiyono" <isk025@student.uit.no>
    Date: Tue, March 14, 2006 2:26 am
    To: rrathbone@aoac.org
    --------------------------------------------------------------------------

    Dear Dr. Rathbone,

    I want to ask you technical questions regarding AOAC's fluorometric
    method* for histamine content analysis.

    "Histamine std solns.-.... (1) Stock solution 1 mg/mL (1000 ppm; assumming
    solution density of 1 kg/L)....(2) Intermediate soln. 10 ug/mL (10
    ppm)....(3) Working solns. 0.5; 1.0, and 1.5 ug/5 mL......"

    My question is:
    --------------------------------
    Why in the manual, 0.1; 0.2; and 0.3 ppm are selected as the calibrating
    points? Why don't we calibrate in the designated range in which
    fluorometer will be used, e.g. from 0 to 60 ppm?

    REFERENCES

    * AOAC. 1990. Histamine in seafood: fluorometric method. Official Method
    of Analysis – AOAC. Vol. 2 Food Composition; Additives; Natural
    Contaminants. 15th ed. AOAC, Arlington. 1298 pp. (pp. 876-877).

    ** Rogers, P.L., and Staruszkiewicz, W. 1997. Gas chromatographic method
    for putrescine and cadaverine in canned tuna and mahi mahi and
    fluorometric method for histamine (minor modification of AOAC Official
    Method 977.13): collaborative study. Journal of AOAC International, 80(3):
    591-602.

    Thank you for the help.

    Best regards,

    Ko, Iwan Setiyono (Ko, I.S. - ISK)
    MSc Candidate - Int. Fisheries Management

    E-mail : isk025@student.uit.no
    Phone : +47 77 64 60 00
    Fax : +47 77 64 60 20
    Mobile : +47 45 00 40 97

    Visiting address:
    Room A-374
    Norwegian College of Fishery Science (NFH)
    University of Tromsø - Breivika N-9037 Tromsø
    NORWAY



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